WebThe phase diagram of the CsHSO4 – CsH2PO4 – H2O ternary system was systematically studied, from which it became possible to synthesize and grow new compounds of mixed sulfate-phosphates of cesium. WebOct 4, 2012 · The approach, combining metal–organic frameworks and functional guests such as proton conductors of M m H n (XO 4) p family has been proposed and successfully realized in the (1 − x)CsHSO 4 –xCr-MIL-101 nanocomposites.. The (1 − x)CsHSO 4 –xCr-MIL-101 (x = 0–0.07) hybrid compounds with unusual transport, structural and …
Entropy Evaluation of the Superprotonic Phase of CsHSO4: …
WebDec 24, 2006 · The entropy of the superprotonic transition (phase II → phase I) of CsHSO4 is evaluated both experimentally and theoretically. Calorimetric measurements reveal a value of 14.75(22) J mol-1 K-1. Under the assumption that the entropy is entirely configurational, arising from both sulfate group orientational disorder and disorder in the … WebCompound Class(es): sulfate Interpretation Detail(s): cell parameters determined and structure type assigned Sample Detail(s): single crystal (determination of cell parameters) derek brockway weatherman walking
Synthesis, structure, and properties of compounds in the …
WebAug 21, 2001 · Exploratory synthesis in the NaHSO4−CsHSO4 system, aimed at discovering novel proton-conducting solids, yielded the new compounds CsNa2(HSO4)3 and Cs2Na(HSO4)3. Thermal analysis demonstrated the absence of phase transitions for both compounds prior to melting. The conductivities of the two compounds vary … WebOct 4, 2012 · Note that conductivity of β-Cs 3 (HSO 4) 2 H 2 PO 4 and the compounds under study (for example, x = 0.33) are comparable in the low-temperature range, while in high-temperature region conductivity values correspond more to CsHSO 4 (I). β-Cs 3 (HSO 4) 2 H 2 PO 4 is known to undergo a superprotonic phase transition at 125 °C with an … WebMar 24, 2003 · Abstract. With an objective to assess the suitability of the dry proton conductor cesium hydrogen sulfate (CsHSO4) as an electrolyte for fuel cells, its chemical stability in H 2 atmosphere in presence of the electrocatalyst Pt/C has been investigated. X-ray diffraction and differential scanning calorimetric (DSC) data indicate that CsHSO4 ... derek brower financial times